Análisis Óptico Comparativo de Capas de Transporte de Carga Orgánicas e Inorgánicas en Celdas Solares de Perovskita

I.Alvarez Samario, R.Reyes Molina, S.Vázquez y Parraguirre, I.Cosme, I.Kudriavtsev, B.Reyes-Ramirez, S.Mansurova

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Información básica

Volumen

V58 - N1 / 2025 Especial: Óptica y Fotónica en México

Referencia

51205

DOI

http://dx.doi.org/10.7149/OPA.58.1.51205

Idioma

English

Etiquetas

Modelado óptico ,celdas solares de perovskita, orgánicas, inorgánicas, capa de transporte de carga

Resumen

Este estudio investiga el rendimiento óptico de celdas solares basadas en perovskita de yoduro de plomo y metilamonio (MAPbI₃) con diferentes conﬁguraciones de las capas de transporte. Se compararon capas orgánicas, incluyendo polietileno-glicol-dioxitiofeno: poliestireno sulfonato(PEDOT:PSS) como capa de transporte de huecos(HTL)y [6,6]-fenil-C61-butirometil éster (PC₆₀BM) como capa de transporte de electrones (ETL), frente a sus contrapartes inorgánicas, óxido de níquel (NiO) como HTL y óxido de zinc (ZnO) como ETL. Las constantes ópticas se obtuvieron ajustando los datos experimentales de transmitancia mediante los modelos Tauc-Lorentz-Drude(TLD) y Tauc-Lorentz(TL). Estas constantes se emplearon para simular la eﬁciencia cuántica externa(EQE) y la densidad de corriente de cortocircuito(Jsc) utilizando la plataforma e-ARC, una herramienta de simulación para evaluar celdas solares de capas múltiples. Se realizaron evaluaciones comparativas de reﬂectancia, pérdidas por absorción parasitaria y su impacto en J_sc para diversas combinaciones de ETL y HTL. Los resultados destacan las ventajas y desventajas en el rendimiento óptico através de las distintas arquitecturas de dispositivos y exploran estrategias para mitigar las pérdidas parasitarias, particularmente mediantela optimización de los grosores de las capas y las propiedades de materiales. Este trabajo ofrece información clave paramejorar la eﬁciencia de las celdas solares de perovskita mediante el modelado óptico integrado y estrategias de dise˜no.

Referencias

J. Y. Kim, J.-W. Lee, H. S. Jung, H. Shin, and N.-G. Park, “High-efficiency perovskite solar cells,” Chemical reviews 120(15), 7867–7918 (2020).

P. Basumatary and P. Agarwal, “A short review on progress in perovskite solar cells,” Materials Research Bulletin 149, 111,700 (2022).

Y. Wang, T. Wu, J. Barbaud, W. Kong, D. Cui, H. Chen, X. Yang, and L. Han, “Stabilizing heterostructures of soft perovskite semiconductors,” Science 365(6454), 687–691 (2019).

E. H. Jung, N. J. Jeon, E. Y. Park, C. S. Moon, T. J. Shin, T.-Y. Yang, J. H. Noh, and J. Seo, “Efficient, stable and scalable perovskite solar cells using poly (3-hexylthiophene),” Nature 567(7749), 511–515 (2019).

J. J. Diaz, I. Ornelas-Cruz, F. J. Cano, S. Velumani, S. Gallardo-Hernández, I. Koudriavtsev, and S. Mansurova, “Analysis of the bonding’s energy in metal-halide perovskites and brief evaluation of meta-GGA functionals TPSS and revTPSS,” Journal of Materials Science 59(6), 2361–2374 (2024).

R. Wang, M. Mujahid, Y. Duan, Z.-K. Wang, J. Xue, and Y. Yang, “A review of perovskites solar cell stability,” Advanced Functional Materials 29(47), 1808,843 (2019).

P. Nandigana, B. Saminathan, P. Sriram, D. Sujatha, B. Subramanian, S. K. Panda, et al., “An ambient process for hole transport layer-free highly stable MAPbI 3 by addition of MACl for efficient perovskite solar cells,” Energy Advances 3(2), 442–450 (2024).

N. R. E. Laboratory, “NREL Best Research-Cell PV Efficiency Chart,” (1976).

Y. Zhao, F. Ma, Z. Qu, S. Yu, T. Shen, H.-X. Deng, X. Chu, X. Peng, Y. Yuan, X. Zhang, and J. You, “Inactive (PbI ) RbCl stabilizes perovskite films for efficient solar cells,” Science 377(6605), 531–534 (2022).

H. Min, D. Y. Lee, J. Kim, G. Kim, K. S. Lee, J. Kim, M. J. Paik, Y. K. Kim, K. S. Kim, M. G. Kim, et al., “Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes,” Nature 598(7881), 444–450 (2021).

T. Bu, J. Li, F. Zheng, W. Chen, X. Wen, Z. Ku, Y. Peng, J. Zhong, Y. Cheng, and F. Huang, “Universal passivation strategy to slot-die printed SnO2 for hysteresis-free efficient flexible perovskite solar module,” Nature Communications 9, 4609 (2018).

L. Duan, S. P. Phang, D. Yan, J. Stuckelberger, D. Walter, Y. Hou, W. Wang, N. Chang, A. D. Bui, A. O. Mayon, L. Chang, D. Kang, T. Duong, R. Basnet, H. Nguyen, T. White, J. Bullock, K. Weber, D. MacDonald, K. Catchpole, and H. Shen, “Over 29%-efficient, stable n–i–p monolithic perovskite/silicon tandem solar cells based on double-sided poly-Si/SiO2 passivating contact silicon cells,” J. Mater. Chem. A 12, 20,006–20,016 (2024). Opt. Pura Apl. 58 (1) 51205 (2025) © Sociedad Española de Óptica ÓPTICA PURA Y APLICADA

M. Jeong, I. W. Choi, K. Yim, S. Jeong, M. Kim, S. J. Choi, Y. Cho, J. H. An, H. B. Kim, and Y. Jo, “Large area perovskite solar cells employing spiro Naph hole transport material,” Nature Photonics 16(2), 119–125 (2022).

M. Kim, I.-w. Choi, S. J. Choi, J. W. Song, S.-I. Mo, J.-H. An, Y. Jo, S. Ahn, S. K. Ahn, G.-H. Kim, et al., “Enhanced electrical properties of Li-salts doped mesoporous TiO2 in perovskite solar cells,” Joule 5(3), 659–672 (2021).

D. Saranin, T. Komaricheva, L. Luchnikov, D. S. Muratov, T. S. Le, Y. Karpov, P. Gostishchev, S. Yurchuk, D. Kuznetsov, S. Didenko, and A. Di Carlo, “Hysteresis-free perovskite solar cells with compact and nanopar-ticle NiO for indoor application,” Solar Energy Materials and Solar Cells 227, 111,095 (2021).

A. Al-Ashouri, E. Köhnen, B. Li, A. Magomedov, H. Hempel, P. Caprioglio, J. A. Márquez, A. B. Morales Vilches, E. Kasparavicius, J. A. Smith, N. Phung, D. Menzel, M. Grischek, L. Kegelmann, D. Skrob-lin, C. Gollwitzer, T. Malinauskas, M. Joˇ st, G. Matiˇ c, B. Rech, R. Schlatmann, M. Topiˇ c, L. Korte, A. Abate, B. Stannowski, D. Neher, M. Stolterfoht, T. Unold, V. Getautis, and S. Albrecht, “Monolithic perovskite/silicon tandem solar cell with ¿29% efficiency by enhanced hole extraction,” Science 370(6522), 1300–1309 (2020).

B. Fan, J. Xiong, Y. Zhang, C. Gong, F. Li, X. Meng, X. Hu, Z. Yuan, F. Wang, and Y. Chen, “A Bionic Interface to Suppress the Coffee-Ring Effect for Reliable and Flexible Perovskite Modules with a Near-90% Yield Rate,” Advanced Materials 34(29), 2201,840 (2022).

H. Zhang and N.-G. Park, “Progress and issues in p-i-n type perovskite solar cells,” DeCarbon 3, 100,025 (2024).

W. Han, G. Ren, J. Liu, Z. Li, H. Bao, C. Liu, and W. Guo, “Recent Progress of Inverted Perovskite Solar Cells with a Modified PEDOT:PSS Hole Transport Layer,” ACS Applied Materials & Interfaces 12(44), 49,297– 49,322 (2020).

K. Kim, M. Kim, H. Lee, D. Chung, and J. Kim, “Multi-Functional PEDOT:PSS as the Efficient Perovskite Solar Cells,” Small (2024).

H. M. Alishah, F. P. G. Choi, and S. Gunes, “Investigation of various commercial PEDOT:PSS (poly(3,4-ethylenedioxythiophene)polystyrene sulfonate) as a hole transport layer in lead iodide-based inverted planar perovskite solar cells,” Journal of Materials Science: Materials in Electronics 32(16), 21,450–21,461 (2021).

N. Cheng, Z. Liu, Z. Yu, W. Li, Z. Zhao, Z. Xiao, B. Lei, S. Sun, and W. Zi, “High performance inverted perovskite solar cells using PEDOT:PSS/KCl hybrid hole transporting layer,” Organic Electronics 98, 106,298 (2021).

G.-J. A. H. Wetzelaer and P. W. M. Blom, “Electron and hole transport in solution-processed fullerenes,” J. Mater. Chem. C 9, 16,068–16,077 (2021).

Y. Wang, S. Dong, Y. Miao, D. Li, W. Qin, H. Cao, L. Yang, L. Li, and S. Yin, “BCP as Additive for Solution-Processed PCBM Electron Transport Layer in Efficient Planar Heterojunction Perovskite Solar Cells,” (2017).

V. H. Diniz Araújo, A. F. Nogueira, J. C. Tristão, and L. J. dos Santos, “Fullerene-C60 and PCBM as interlay-ers in regular and inverted lead-free PSCs using CH3NH3SnI3: an analysis of device performance and defect density dependence by SCAPS-1D,” RSC Adv. 14, 10,930–10,941 (2024).

V. V. Ozerova, A. V. Mumyatov, A. E. Goryachev, E. A. Khakina, A. S. Peregudov, S. M. Aldoshin, and P. A. Troshin, “Rational Design of Fullerene Derivatives for Improved Stability of p-i-n Perovskite Solar Cells,” Inorganics 11(4) (2023).

A. Corani, M.-H. Li, P.-S. Shen, P. Chen, T.-F. Guo, A. El Nahhas, K. Zheng, A. Yartsev, V. Sundström, and C. S. Ponseca, “Ultrafast Dynamics of Hole Injection and Recombination in Organometal Halide Perovskite Using Nickel Oxide as p-Type Contact Electrode,” The Journal of Physical Chemistry Letters 7(7), 1096–1101 (2016).

J. H. Heo, S.-C. Lee, S.-K. Jung, O.-P. Kwon, and S. H. Im, “Efficient and thermally stable inverted perovskite solar cells by introduction of non-fullerene electron transporting materials,” J. Mater. Chem. A 5(39), 20,615– 20,622 (2017).

Y. Rong, Y. Hu, S. Ravishankar, H. Liu, X. Hou, Y. Sheng, A. Mei, Q. Wang, D. Li, M. Xu, J. Bisquert, and H. Han, “Tunable hysteresis effect for perovskite solar cells,” Energy & Environmental Science 10(11), 2383–2391 (2017).

D. S. Saranin, V. N. Mazov, L. O. Luchnikov, D. A. Lypenko, P. A. Gostishev, D. S. Muratov, D. A. Podgorny, D. M. Migunov, S. I. Didenko, M. N. Orlova, D. V. Kuznetsov, A. R. Tameev, and A. Di Carlo, “Tris(ethylene Opt. Pura Apl. 58 (1) 51205 (2025) © Sociedad Española de Óptica ÓPTICA PURA Y APLICADA diamine) nickel acetate as a promising precursor for hole transport layer in planar structured perovskite solar cells,” Journal of Materials Chemistry C 6(23), 6179–6186 (2018).

R. Reyes-Molina, J. C. Carrillo-Sendejas, S. Mansurova, and I. Cosme, “Effect of PEDOT:PSS optical prop-erties at the frontal interface on electrical performance in MAPbI3 perovskite solar cells,” Optical Materials 150, 115,299 (2024).

W.-C. Lai, K.-W. Lin, T.-F. Guo, P. Chen, and Y.-Y. Liao, “Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure,” AIP Advances 8(1), 015,109 (2018).

H. Fujiwara and R. W. Collins, eds., Spectroscopic Ellipsometry for Photovoltaics, vol. 212 of Springer Series in Optical Sciences (Springer International Publishing, Cham, 2018).

H. Fujiwara and R. W. Collins, “Spectroscopic Ellipsometry for Photovoltaics Volume 2: Applications and Optical Data of Solar Cell Materials,” .

A. Nakane, H. Tampo, M. Tamakoshi, S. Fujimoto, K. M. Kim, S. Kim, H. Shibata, S. Niki, and H. Fujiwara, “Quantitative determination of optical and recombination losses in thin-film photovoltaic devices based on external quantum efficiency analysis,” Journal of Applied Physics 120, 064,505 (2016).

J. You, L. Meng, T. B. Song, T. F. Guo, W. H. Chang, Z. Hong, H. Chen, H. Zhou, Q. Chen, Y. Liu, N. D. Marco, and Y. Yang, “Improved air stability of perovskite solar cells via solution-processed metal oxide trans-port layers,” Nature Nanotechnology 11, 75–81 (2016).

J. H. Kim, P. W. Liang, S. T. Williams, N. Cho, C. C. Chueh, M. S. Glaz, D. S. Ginger, and A. K. Jen, “High-performance and environmentally stable planar heterojunction perovskite solar cells based on a solution-processed copper-doped nickel oxide hole-transporting layer,” Advanced Materials 27, 695–701 (2015).

F. M. Rombach, S. A. Haque, and T. J. Macdonald, “Lessons learned from spiro-OMeTAD and PTAA in perovskite solar cells,” (2021).

H. Zhang and J. Toudert, “Optical management for efficiency enhancement in hybrid organic-inorganic lead halide perovskite solar cells,” (2018).

S.-E. Hsu, W.-X. Zhu, D.-T. Wu, W.-L. Huang, L.-T. Xue, C.-J. Huang, C.-H. Wang, Y.-S. Li, W.-J. Qiu, and C.-T. Lin, “Reducing optical reflection loss through textured PEDOT:PSS in hybrid Sn–Pb perovskite solar cells,” Sustainable Energy & Fuels 8, 1712–1718 (2024).

Z. Gao, G. Feng, T. Gao, G. Wu, L. Ding, and H. Zhou, “Double moth-eye structures to reduce parasitic absorbed and reflected in homojunction perovskite solar cells,” Current Applied Physics 61, 25–33 (2024).

B. Montaño, J. J. Diaz, I. Koudriavtsev, I. Cosme, N. Korneev, and S. Mansurova, “In-depth study of the effect of annealing temperature on the structural, chemical, and optical properties of MAPI thin films prepared by a one-step deposition method,” Journal of Materials Science: Materials in Electronics 34(12), 1016 (2023).